MyPaint - MyPaint is a fast, distraction-free, and easy painting tool for digital artists.
IcoFX - IcoFX is an all-in-one solution for icon creation, extraction and editing.
Corel Painter - Corel Painter is media painting software.
IconsExtract - Extract icons and cursors stored in EXE, DLL, OCX, CPL files
Krita - Krita is a professional FREE and open source painting program. It is made by artists that want to seaffordable art tools for everyone. Concept art. texture and matte painters, illustrations and comics.
Iconsflow - Iconsflow helps users to design outlined, solid, webby and flat icons